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分子量


分子量测量原理:静态光散射法

ZHONGSUOZHOUZHI,JINGTAIGUANGSANSHEFAKEYIQINGSONGCELIANGJUEDUIFENZILIANG。

CELIANGYUANLIWEI,JIANGGUANGXIANZHAOSHEZAIRONGYEFENZISHANGKEYIDEDAOSANSHEGUANG, GENJUSANSHEGUANGDEJUEDUIZHIQIUQUFENZILIANG。JILIYONGLEDAFENZIKEDEDAO QIANGSANSHEGUANG,XIAOFENZIKEDEDAORUOSANSHEGUANGDEXIANXIANG。

SHIJISHANG,YINWEINONGDUBUTONGSANSHEGUANGQIANGDUBUTONG,SHICESHUDIANBUTONGNONG DURONGYEDEGUANGSANSHEQIANGDU,DAIRUYIXIAGONGSHIHUIZHITUSHI。HENGZHOUWEINONGDU,ZONGZHOUWEIYUSANSHEQIANGDUKc/R(θ)XIANGDENGDIDAOSHU。CIFANGFAYEBEICHENGWEIDebyeTUSHIFA。

JIEYOUWANGLINGNONGDU(C=0)WAICHADEDAOSHUQIUQUFENZILIANGMw,BINGYICICHUQITIDUKEQIUDEDIERWEILIXISHUA2。

FENZILIANGJIAODADEFENZI,SANSHEQIANGDUHUIYINJIAODUERBUTONG。

FENZILIANGJIEYOUCELIANGBUTONGSANSHEJIAODU(θ)DESANSHEQIANGDUBUDANKETIGAO CELIANGJINGDU,YEKEHUODEFENZIKUOSANZHIBIAOZHIDEHUIZHUANBANJING。YIGUDINGJIAODUJINXINGCELIANGSHI,ZHIYAOSHURUTUICEDEHUIZHUANBANJING,JIAODUJIANGZIXINGBUZHENG,KECELIANGGENGGAOJINGDUDEFENZILIANG。


第二维里系数

BIAOSHIRONGMEIZHONGFENZIJIANDEPAICHIYUXIYINCHENGDU,GENGYIYUGUANCHARONGJIFENZIDEXIANG RONGXINGYUJIEJINGHUAXIANXIANG。

● A2WEIZHENGSHI,DAIBIAORONGJIXIANGRONGXINGGAO,FENZIJIANPAICHILIQIANG,GENGJIAWENDING

● A2WEIFUSHI,DAIBIAORONGJIXIANGRONGXINGDI,FENZIJIANXIYINLIQIANG,YICHANSHENGNINGJU。

● A2=0SHI,DAIBIAORONGJIWEILIXIANGRONGJI,CISHIWENDUBEICHENGWEILIXIANGWENDU。PAICHILIYUXIYINLICHUYUPINGHENGZHUANGTAI,YICHANSHENGJIEJINGHUA。